Quaternary Cu (InxGa1-x) Se2 Nanoparticles Synthesis Using Heating-up Method for Photovoltaic Applications

نویسندگان

  • Hadi Zarei Department of Physics, Faculty of Basic Sciences, Tarbiat Modares University,
  • Rasoul Malekfar Department of Physics, Faculty of Basic Sciences, Tarbiat Modares University,
چکیده مقاله:

In this paper, tetragonal chalcopyrite (CIGS) Cu(InxGa1-x)Se2 with x=0, 0.5, 0.8, 1 are synthesized by heating-up method. These nanoparticle structures differ in morphology and absorption properties due to the synthesis temperatures of 250, 255, 260, 265, 270 and 280 ºC, and gallium molar ratio over the total gallium and indium contents. These features are studied using scanning electron microscope, X-ray diffraction and absorption spectroscopy in visible, ultra-violet and near-infrared wavelengths. Results indicate that by increasing gallium content, absorption edge rises toward the visible light. Any modification in the absorption edge changes the band gap and as a result the energy gap and the absorption of cell increases considerably. Also in the heating-up method, increasing the reaction temperature improves nanoparticles crystallites. This leads the absorption improvement and higher cells efficiency. Produced nanoparticles are spherical shape with are varying the diameter around 30-80 nm.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of Cu Doped NiO Nanoparticles by Chemical Method

The Cu doped NiO (NiO:Cu) nanoparticles were synthesized by co-precipitation method using NiCl2.6H2O, CuCl2.2H2O for Ni and Cu sources, respectively. Sodium hydroxide has been used as a precipitator agent. Effect of Cu doping agent on the structural and optical properties of nanostructures were characterized by XRD, SEM, AFM, spectrophotometry, FTIR a...

متن کامل

New combustion synthesis technique for the production of (InxGa1-x)2O3 powders: Hydrazine/metal nitrate method

A new low-temperature method to produce (InxGa1−x)2O3 (x 4 0.1, 0.2, and 0.3) powders with high purity, high chemical homogeneity and improved crystallinity in the as-synthesized state has been developed. This procedure produced finely divided powders through an exothermic reaction between the precursors. The process starts with aqueous solutions of In(NO3)3 and Ga(NO3)3 as the precursors and h...

متن کامل

Synthesis of Cu-CuO and Cu-Cu2O Nanoparticles via Electro-Explosion of Wire Method

   We report an investigation on the synthesis of Copper Oxide nanostructures via the Electro-Explosion of Wire method. Cu-CuO and Cu-Cu2O nanoparticles with mean particle size of 21.1 to 59.1 nm were synthesized by changing the applied current density and amount of used Tetra Methyl Ammonium Hydroxide as the surfactant. The X-ray diffraction analysis, field emission scanning ele...

متن کامل

Growth of Cu(In,Ga)Se2 Films Selenized Using Dimethylselenium

Cu(In,Ga)Se2 (CIGS) films were prepared by thermal treatment of In/CuGa metallic precursors using dimethylselenium, which is a less hazardous Se source than H2Se gas. CIGS films were fabricated using various heating times and dimethylselenium supply rates. We investigated the effect of the selenization temperature and the dimethylselenium supply rate on the crystal phase and surface morphology ...

متن کامل

Keratin nanoparticles: synthesis and application for Cu(II) removal

A straightforward procedure to synthesize keratin nanoparticles (KNP) from chicken feathers was introduced. The characterization of the synthesized nanoparticles was done using Fourier transform infrared (FTIR) spectroscopy, dynamic light scattering (DLS), X-ray diffraction (XRD) patterns and transmission electron microscopy (TEM). The FTIR analysis revealed no significant chemical change after...

متن کامل

From hot-injection synthesis to heating-up synthesis of cobalt nanoparticles: observation of kinetically controllable nucleation.

Monodisperse nanoparticles of well-defined size and shape are required in several emerging applications, which take advantage of their size-dependent properties such as the superparamagnetic limit in the case of magnetic nanoparticles. Accurate tuning of the nanoparticle size and shape requires understanding of the mechanisms involved in particle nucleation and growth. In spite of extensive ong...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 12  شماره None

صفحات  13- 20

تاریخ انتشار 2018-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

کلمات کلیدی

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023